Strain crystallization

Strain crystallization is a phenomenon in which an initially amorphous solid material undergoes a phase transformation due to the application of strain. Strain crystallization occurs in natural rubber, and some other elastomers. The phenomenon has important effects on strength and fatigue properties. There are various techniques for measuring crystallization in rubber, including: x-ray diffraction, specific heat changes, and density changes.

Elastomers that Strain Crystallize

Elastomers that Do Not Strain Crystallize

Sources